Use the 'string method' and get it as straight as you can, then drive it some and see what you think. When everything else is finished, then you can decide on alignment.
I have 2 GB, about 1300+ docs for you.
It is a GOOD idea, but someone has to do the work to keep it up or it will be like the older GM UPFITTERs files.
enter this in your browser as a URL:
gm upfitter 2003 electrical manual full size
The older truck listings are all mixed up and very hard to find what you want.
MAF, MAT, ECT, etc all the usual suspects. How's the boost? If you demand full fuel pressure with your scanner, will it max out the actual fuel pressure?
It is surprising how much stuff can make its way through the other devices and end up on the radiator. I think you will be happy with the work that you have done.
Download the electrical manual here: Note that the manual covers 2003-2006
https://www.gmupfitter.com/wp-content/uploads/2021/05/2006_LD_CKFullSizeElectrical.pdf